The NX-01 Enterprise was captained by Jonathan Archer.
The original USS Enterprise had five captains: Robert April, Christopher Pike, and of course, James Kirk. After the refit of 2270 or so, Captain Willard Decker & Spock were also assigned as captains of the Enterprise.
The Enterprise-A was also Kirk.
The Enterprise-B was captained by John Harriman.
The C was commanded by Rachel Garrett, replaced by Richard Castillo as acting captain.
Captain Jean-Luc Picard was in charge of the D and E.
Will Riker was given a field promotion to captain of the Enterprise during the Borg Incursion 2366-67.
Captain Edward Jellico was given command of the Enterprise-D briefly in 2369. TrekFan1984 Ends (talk) 22:31, April 23, 2015 (UTC)