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I would say T'Pal, from Enterprise with Capt. John Archer.

Ambassador V'Lar from ENT: Fallen Hero greeted Captain Archer with a handshake. She did say LLAP to T'Pol at the end of the episode.

I'm not sure about the emotional vulcans from enterprise, (the one where T'Pol mind melds) it's been a while since I've seen that one. (episode citation needed)

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