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The realm of the 5 series' and the films, no. But Q and Spock did appear in a couple of audiobooks named, aptly Spock Vs Q, but these are considered non-canon.

There were rumors in some forums that the "squire of gothos" was a Q.

Read "Q Squared" it has lots of crossovers between various timelines.


There is a theory among fandom that Trelane, the Squire of Gothos (ST:TOS "The Squire of Gothos") was of the Q.

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